EN 10095 Specification

Scope

This Standard Specification covers the grades of wrought steels and nickel alloys listed in Tables below which are usually employed for products, for which the main requirement is their resistance to the effects of hot gases and products of combustion at temperatures above 550 8C. EN 10095 specifies the technical delivery conditions for semi-finished products, for hot or cold rolled sheet/plate and strip, hot or cold formed bars, rods and sections of heat resisting steels and nickel alloys.
Materials covered in this European Standard are classified according to their structure into:
– ferritic steels.
– austenitic-ferritic steels.
– austenitic steels.
– austenitic nickel alloys.

Chemical composition (cast analysis)1 of ferritic heat-resisting steels

Steel designation% by mass
NameNumberCSiMn
max.
P
max.
S
max.
CrA1Others
X10CrAlSi71.4713max. 0.120.50 to 1.001.000.0400.0156.00 to 8.000.50 to 1.00 
X10CrAlSi131.4724max. 0.120.70 to 1.401.000.0400.01512.00 to 14.000.70 to 1.20
X10CrAlSi181.4742max. 0.120.70 to 1.401.000.0400.01517.00 to 19.000.70 to 1.20
X10CrAlSi251.4762max. 0.120.70 to 1.401.000.0400.01523.00 to 26.001.20 to 1.70
X18CrN281.47490.15 to 0.20max. 1.001.000.0400.01526.00 to 29.00N: 0.15 to 0.25
X3CrAlTi18-21.4736max. 0.04max. 1.001.000.0400.01517.00 to 18.001.70 to 2.100.2 + 4(C + N) ≤ Ti ≤ 0.80

Chemical composition (cast analysis)1 of austenitic-ferritic and austenitic heat-resisting steels

Steel designation% by mass
NameNumberCSiMnP
max.
S
max.
CrNiNOthers
Austenitic heat-resisting steels
X8CrNiTi18-101.4878max. 0.10max. 1.00max. 2.000.0450.01517.00 to 19.009.00 to 12.00 Ti: 5 X % C ≤ Ti ≤ 0.80
X15CrNisi20-121.4828max. 0.201.50 to 2.50max. 2.000.0450.01519.00 to 21.0011.00 to 13.00max. 0.11 
X9CrNiSiNCe21-11-21.48350.05 to 0.121.40 to 2.50max. 1.000.0450.01520.00 to 22.0010.00 to 12.000.12 to 0.20Ce: 0.03 to 0.08
X12CrNi23-131.4833max. 0.15max. 1.00max. 2.000.0450.01522.00 to 24.0012.00 to 14.00max. 0.11 
X8CrNi25-211.4845max. 0.10max. 1.50max. 2.000.0450.01524.00 to 26.0019.00 to 22.00max. 0.11 
X15CrNiSi25-211.4841max. 0.201.50 to 2.50max. 2.000.0450.01524.00 to 26.0019.00 to 22.00max. 0.11 
X12NiCrSi35-161.4864max. 0.151.00 to 2.00max. 2.000.0450.01515.00 to 17.0033.00 to 37.00max. 0.11 
X10NiCrAlTi32-211.4876max. 0.12max. 1.00max. 2.000.0300.01519.00 to 23.0030.00 to 34.00 A1: 0.15 to 0.60
Ti: 0.15 to 0.60
X6NiCrNbCe32-271.48770.04 to 0.08max. 0.30max. 1.000.0200.01026.00 to 28.0031.00 to 33.00max. 0.11A1: max. 0.025
Ce : 0.05 to 0.10
Nb:0.60 to 1.00
X25CrMnNiN25-9-71.48720.20 to 0.30max. 1.008.00 to 10.000.0450.01524.00 to 26.006.00 to 8.000.20 to 0.40 
X6CrNiSiNCe19-101.48120.04 to 0.081.00 to 2.00max. 1.000.0450.01518.00 to 20.009.00 to 11.000.12 to 0.20Ce: 0.03 to 0.08
X6NiCrSiNCe35-25*)1.48540.04 to 0.081.20 to 2.00max. 2.000.0400.01524.00 to 26.0034.00 to 36.000.12 to 0.20Ce: 0.03 to 0.08
X10NiCrSi35-191.4886max. 0.151.00 to 2.00max. 2.000.0300.01517.00 to 20.0033.00 to 37.00max. 0.11 
X10NiCrSiNb35-221.4887max. 0.151.00 to 2.00max. 2.000.0300.01520.00 to 23.0033.00 to 37.00max. 0.11Nb: 1.00 to 1.50
Austenitic-ferritic heat-resisting steel
X15CrNiSi25-41.48870.10 to 0.200.8 to 1.50max. 2.000.0400.01524.50 to 26.503.50 to 5.50max. 0.11

Chemical composition (cast analysis)1) of austenitic nickel alloys

Alloys designation% by mass
NameNumberCMn
max
Si
max
P
max.
S
max.
NiCrCoFeMoA1TiCu
max.
Nb + TaB
max.
Ce
NiCr15Fe2.48160.05 to 0.101.000.500.0200.015min. 72.0014.00 to 17.002)6.00 to 10.00 max. 0.30max. 0.300.50   
NiCr20Ti2.48510.08 to 0.151.001.000.0200.015Rest18.00 to 21.00max. 5.00max. 5.00 max. 0.300.20 to 0.600.50   
NiCr22Mo9Nb2.48560.03 to 0.100.500.500.0200.015min. 58.0020.00 to 23.00max. 1.00max. 5.008.00 to 10.00max. 0.40max. 0.400.503.15 to 4.15  
NiCr23Fe2.48510.03 to 0.101.000.500.02058.00 to 63.00min. 58.0021.00 to 25.002)max. 18.00 1.00 to 1.70max. 0.500.50 0.006 
NiCr28FeSiCe2.48890.05 to 0.121.002.50 to 3.000.0200.010min. 45.0026.00 to 29.002)21.00 to 25.00   0.30  0.03 to 0.09

1)Elements not listed in the table may not be intentionally added to the alloy
without the agreement of the purchaser except for finishing the cast. All appropriate
precautions
are to be taken to avoid addition of such elements from scrap and other materials used in
production which would impair mechanical properties and the suitability of the alloy.

2) A maximum of 1,5 % Co is allowed and counted as nickel. Reporting of cobalt is not required.

*) Patented steel grade.

Mechanical Properties

DesignationProductsHeat
treatment
conditions
HB max.
1) 2) 3)
Proof strengthTensile strengthA % min.
NameNumberFormThickness 𝘢
or diameter
𝘥 mm
Rp0.2
N/mm2
Rp1.0
N/mm2
Rm
N/mm2
Long productsFlat products
min 3)min 3)1)3)0.5 ≤ a ≤ 3
1, tr
3 < a
1tr
Ferritic heat resisting steels
X10CrAlSi71.4713flat productsa ≤ 12+A192220 420 to 620202015
X10CrAlSi131.4724+A192250 450 to 65015131515
X10CrAlSi181.4742barsd ≤ 25+A212270 500 to 70015131515
X10CrAlSi251.4762+A223280 520 to 72010131515
X18CrN281.4749rods and sectionsd ≤ 25+A212280 500 to 70015131515
X3CrAlTi18-21.4736+A200280 500 to 650252525
Austenitic heat resisting steels
X8CrNiTi18-101.4878flat productsa ≤ 75+A215190230500 to 720401)4040
X15CrNiSi20-121.4828+A223230270550 to 750301)4040
X9CrNiSiNCe21-11-21.4835+A210310350650 to 850401)3740
X12CrNi23-131.4833+A192210250500 to 700351)3335
X8CrNi25-211.4845barsd ≤ 160+A192210250500 to 700351)3335
X15CrNiSi25-211.4841+A223230270550 to 750301)2830
X12NiCrSi35-161.4864+A223230270550 to 750301)2830
X10NiCrAlTi32-211.4876+A192170210450 to 680301)2830
X6NiCrNbCe32-271.4877+A223180220500 to 750351)
X25CrMnNiN25-9-71.4872rods and
sections
a ≤ 72+A311500540850 to 1050251)
X6CrNiSiNCe19-101.4818+A210290330600 to 800401)3040
X6NiCrSiNCe35-251.4854+A210300340650 to 850401)4040
X10NiCrSi35-191.4886+A200270300500 to 65040
X10NiCrSiNb35-221.4887+A200270300500 to 65040
Austenitic-ferritic heat resisting steel
X15CrNiSi25-41.4821flat productsa ≤ 12+AT225400600 to 850161612
barsd ≤ 60
rodsd ≤ 25
Heat resisting nickel alloys
NiCr15Fe2.4816flat productsa ≤ 75+AT200240550 to 850303030
barsd ≤ 160
rodsd ≤ 25
NiCr20Ti2.4951flat productsa ≤ 75+AT230240650 to 8503030
barsd ≤ 160
rodsd ≤ 25
NiCr22Mo9Nb2.4856flat products3 ≤ a < 75+AT240380760 to 1003030
a < 3415820 to 105030
bars100 < d ≤ 250345760 to 100025
d ≤ 100415820 to 105030
rodsd ≤ 25415820 to 105030
NiCr23Fe2.4851flat productsa ≤ 75+AT220205550 to 750303030
barsd ≤ 160
rodsd ≤ 25
NiCr28FeSiCe2.4889flat productsa ≤ 50+AT220240620 to 82035353535
barsd ≤ 160

1) The maximum HB values may be raised by 100 units or the maximum tensile strength value may
be raised by 200 N/mm2 and the minimum elongation value be lowered to 20 % for
sections and bars of ≤ 35 mm thickness having a final cold deformation.

2) For guidance only.

3) For rods, only the tensile strength values apply.

Heat Treatments

DesignationHeat Treatments
NameNumberSymbol1)Temperatures2)
°C
Type of cooling3)
Ferritic heat resisting steels
X10CrAlSi71.4713+A780 to 840a, w 4)
X10CrAlSi131.4724+A800 to 860a, w 4)
X10CrAlSi181.4742+A800 to 860a, w 4)
X10CrAlSi251.4762+A800 to 860a, w 4)
X18CrN281.4749+A800 to 860a, w 4)
X3CrAlTi18-21.4736+A870 to 930a
Austenitic heat resisting steels6)
X8CrNiTi18-101.4878+AT1 020 to 1 120W, a5)
X15CrNiSi20-121.4828+AT1 050 to 1 150W, a5)
X9CrNiSiNCe21-11-21.4835+AT1 020 to 1 120W, a5)
X12CrNi23-131.4833+AT1 050 to 1 120W, a5)
X8CrNi25-211.4845+AT1 050 to 1 120W, a5)
X15CrNiSi25-211.4841+AT1 050 to 1 120W, a5)
X12NiCrSi35-161.4864+AT1 020 to 1 120W, a5)
X10NiCrAlTi32-211.4876+AT1 050 to 1 120W, a5)
X6NiCrNbCe32-271.4877+AT1 050 to 1 120W, a5)
X25CrMnNiN25-9-71.4872+AT1 050 to 1 120W, a5)
X6CrNiSiNCe19-101.4818+AT1 020 to 1 120W, a5)
X6NiCrSiNCe35-251.4854+AT1 100 to 1 150W, a5)
X10NiCrSi35-191.4886+AT1 050 to 1 150W, a5)
X10NiCrSiNb35-221.4887+AT1 050 to 1 150W, a5)
Austenitic-ferritic heat resisting steel
X15CrNiSi25-41.4821+AT1 000 to 1 100W, a5)
Heat resisting nickel alloys
NiCr15Fe2.4816+A950 to 1 000W, a5)
NiCr20Ti2.4951+AT1 000 to 1 050W, a5)
NiCr22Mo9Nb2.4856+A950 to 1 000W, a5)
NiCr23Fe2.4851+AT1 100 to 1 200W, a5)
NiCr28FeSiCe2.4889+AT1 150 to 1 200W, a5)

1) A = annealed; AT = solution annealed.

2) If heat treatment is carried out in a continuous furnace, the upper part of the range
specified is usually preferred or even exceeded.

3) a = air; w = water.

4) In special cases furnace cooling is also permitted.

5) Cooling sufficiently rapid.

6) Heat treatment is not required in each case since the material will be exposed to high
temperature when in operation.

Maximum Application Temperature Ta For Air

DesignationTamax.
°C
NameNumber
Ferritic heat resisting steels
X10CrAlSi71.47138002)
X10CrAlSi131.47248502)
X10CrAlSi181.47421 0002)
X10CrAlSi251.47621 1502)
X18CrN281.47491 100
X3CrAlTi18-21.47361 000
Austenitic heat resisting steels
X8CrNiTi18-101.48788502)
X15CrNiSi20-121.48281 0002)
X9CrNiSiNCe21-11-21.48351 150
X12CrNi23-131.48331 0002)
X8CrNi25-211.48451 0502)
X15CrNiSi25-211.48411 1502)
X12NiCrSi35-161.48641 1002)
X10NiCrAlTi32-211.48761 1002)
X6NiCrNbCe32-271.48771 1502)
X25CrMnNiN25-9-71.48721 1502)
X6CrNiSiNCe19-101.48721 050
X6NiCrSiNCe35-251.48541 170
X10NiCrSi35-191.48861 100
X10NiCrSiNb35-221.48871 100
Austenitic-ferritic heat resisting steel
X15CrNiSi25-41.48211 1002)
Heat resisting nickel alloys
NiCr15Fe2.48161 1502)
NiCr20Ti2.49511 150
NiCr22Mo9Nb2.48561 000
NiCr23Fe2.48511 2002)
NiCr28FeSiCe2.48891 200

1) See Creep Properties For 1% Elongation Table.

2) The loss of metal caused by scaling does not exceed 1 g/m2.h at Ta,
and does not exceed 2 g/m2 at Ta + 50 °C on average for a
period of 120 h with four intermediate coolings.

Creep Properties Estimated average value of the strength for 1% elongation at elevated temperature1

DesignationHeat
treatment
Elongation 1 % in 1000 hElongation 1 % in 10 000 hElongation 1 % in 100 000 h
NameNumber500°C600°C700°C800°C900°C1000°C500°C600°C700°C800°C900°C1000°C500°C600°C700°C800°C900°C1000°C
Ferritic heat resisting steels
X10CrAlSi71.4713                  
X10CrAlSi131.4724                  
X10CrAlSi181.4742+A8027.58.53.71.8 5017.54.72.11.0      
X10CrAlSi251.4762                  
X18CrN281.4749                  
X3CrAlTi18-21.4736                  
Austenitic heat resisting steels
X8CrNiTi18-101.4878+AT 1104515   853010       
X15CrNiSi20-121.4828+AT 12050208  8025104      
X9CrNiSiNCe21-11-21.4835+AT 170663115.5(8) 126451910(5) 8026116(3)
X12CrNi23-131.4833+AT 10040188  7025105       
X8CrNi25-211.4845+AT 100451810  9030104       
X15CrNiSi25-211.4841+AT 1055023103 9535104       
X12NiCrSi35-161.4864+AT 105502512  8035155  401441.5 
X10NiCrAlTi32-211.4876+AT 130703013  9040155       
X6NiCrNbCe32-271.4877+AT                  
X25CrMnNiN25-9-71.4872+AT  55154   3482       
X6CrNiSiNCe19-101.4818+AT 14761259(2.5) 12642155(1.7) 802693(1.0)
X6NiCrSiNCe35-251.4854+AT 150602612.56.5 88341584.5 52219.75.13.0
X10NiCrSi35-191.4886+AT 110602612  60352010(4)      
X10NiCrSiNb35-221.4887+AT 110602612  60352010(4)      
Austenitic-ferritic heat resisting steel
X15CrNiSi25-41.4821+AT8027.58.53.71.8 5017.54.72.11.0       
Heat resisting nickel alloys
NiCr15Fe2.4816+A      1539143188 1266628124 
NiCr28FeSiCe2.4889+A        2511.95.93.1  167.23.51.9

Creep Properties Estimated average value of the strength for rupture at elevated temperature1

DesignationHeat
treatment
Rupture 1 % in 1000 hRupture 1 % in 10 000 hRupture 1 % in 100 000 h
NameNumber500°C600°C700°C800°C900°C1000°C500°C600°C700°C800°C900°C1000°C500°C600°C700°C800°C900°C1000°C
Ferritic heat resisting steels
X10CrAlSi71.4713                   
X10CrAlSi131.4724                   
X10CrAlSi181.4742+A16055177.53.6 100359.54.31.9 552052.31.0 
X10CrAlSi251.4762                   
X18CrN281.4749                   
X3CrAlTi18-21.4736                   
Austenitic heat resisting steels
X8CrNiTi18-101.4878+AT 2008830   1424815   652210  
X15CrNiSi20-121.4828+AT 190753515  12036188.5  65167.53 
X9CrNiSiNCe21-11-21.4835+AT 2381055024(12) 157632713(7) 8835158(4)
X12CrNi23-131.4833+AT 190753515  12036188.5  65167.53 
X8CrNi25-211.4845+AT 170803515  13040188.5  801873 
X15CrNiSi25-211.4841+AT 1709040205 130402010  801873 
X12NiCrSi35-161.4864+AT 180753515  12545208  7525731.5
X10NiCrAlTi32-211.4876+AT 200904520  152683010  11448218 
X6NiCrNbCe32-271.4877+AT       175802410(3.5) 14052165(1.5)
X25CrMnNiN25-9-71.4872+AT  802611   45125       
X6CrNiSiNCe19-101.4818+AT 2381054618(7) 157632510(4) 8835145(1.5)
X6NiCrSiNCe35-251.4854+AT 20084412212 1275628158 8036189.24.8
X10NiCrSi35-191.4786+AT 190804322  130552613       
X10NiCrSiNb35-221.4887+AT 190804322  130552613       
Austenitic-ferritic heat resisting steel
X15CrNiSi25-41.4821+AT16055177.53.6 1003.59.54.31.9       
Heat resisting nickel alloys
NiCr15Fe-42.4816+A 1609638221129713863291372159742177 
NiCr20Ti2.4951+AT   372011 1003617106 682311.575
NiCr22Mo9Nb2.4956+A  26010734   1906320       
NiCr23Fe2.4851+AT 2641536020  20510131105 156551742
NiCr28FeSiCe2.4889+AT        40199.55.9  28135.93

1) Values in parentheses involve time and/or stress extrapolation.